Lecithin Applications
Pioneering Lecithin Performance
For more than sixty years, American Lecithin Company (ALC) has been
advancing lecithin technology. We are continually involved in modifying the
basic properties of lecithin to create new products that will provide better
performance for more applications in a wide range of industries.
Since the innovation of lecithin fractionation technology in the 1980s, ALC
has provided the broadest, most versatile line of lecithin-based products in
the market place. From standard grade lecithin to modified lecithin
fractions, we are committed to providing the very best in quality,
consistency and technical support.
An Overview of ALC
- Founded in 1928
-
Pioneered the use of lecithin
products and services in food processing and many other industrial
applications
- Introduced ALCOLEC®, a
series of natural soybean lecithin products which set the industry
standard for quality and consistency
ALC's performance products
include:
Emulsifiers
Dispersants
Wetting agents
Viscosity modifiers
Release aids
Surfactants
Nutritional supplements
The food industry has long
recognized the importance of lecithin as a critical component in processing.
Lecithin helps smooth the texture of food items such as chocolate and
margarine and makes instant foods easy to dissolve.
Some of the food items, which
most frequently incorporate lecithin, are:
Baked goods
Confections
Infant formulas
Cheese products
Industrial applications range
from paints and coatings and plastics to cosmetics and magnetic tape media.
A Safe, Natural Nutrient
Beyond its functional
characteristics, lecithin has added value because of its well established
nutritional value. The phospholipids in lecithin are considered essential
nutrients for proper functioning of the human body.
Unique Chemistry and
Properties
Soybean lecithin is a complex mixture of phospholipids, glycolipids,
triglycerides, sterols and small quantities of fatty acids, carbohydrates
and sphingolipids.
The primary phospholipid
components of lecithin are:
- Phosphatidylcholine (PC)
(13%-18%)
- Phosphatidylethanolamine
(PE) (10%-15%)
- Phosphatidylinositol (PI)
(10%-15%)
- Phosphatidic acid (PA)
(5%-12%)
The separation or
"fractionation" of complex mixtures of lecithin can create new products with
functionality that can be optimized to specific applications. Special grades
of lecithin may include other elements such as refined oils or other
surfactants.
Labeling Issues
As a natural product, lecithin offers food processors a number of labeling
advantages. Products containing lecithin are “Generally
Recognized As Safe” (GRAS) under 21 CFR 184.1400 and specifications of the
Food Chemicals Codex. The FDA-preferred designation is "Soy Lecithin"
although "Lecithin" is often used.
Lecithin products that have
been chemically modified sometimes require special labeling. When they have
been hydroxylated, lecithin should be identified as "Hydroxylated Soy
Lecithin" or "Hydroxylated Lecithin". When enzymatically modified, the
phrase "Enzymatically Modified Lecithin" should appear on labeling.
LECITHIN FUNCTIONS
Emulsification
The unique surface-active properties of lecithin make it ideal for
emulsification. An emulsion is a stable blend of materials that do not mix
easily, tending to separate.
Emulsions are produced through
dispersing one immiscible phase in another by mixing, colloidal milling or
homogenization. The presence of emulsifying agents maintains the stability
of this dispersion.
The primary types of emulsions
are oil-in-water (o/w) and water-in-oil (w/o).
Typical Emulsion
Oil-in-Water
Emulsions
|
Water-in-Oil
Emulsions
|
Mayonnaise |
Margarine and
Spreads |
Infant Formulas |
Icings and
Frostings |
Hand and Body
Lotions |
Petroleum Emulsions |
The emulsification properties
of different lecithin products are a function of their "hydrophilic-lipophilic
balance" (HLB). The HLB describes the relative composition of the
water-loving (polar) and fat-loving (non-polar) elements of an emulsifier
such as lecithin.
Typically, lecithin products
are added to the oil phase for oil-in- water emulsions. In water-in-oil
emulsions, they must be added to the oil phase. Depending on the type of
lecithin being used, heating to 120°f will aid in dispersion and can improve
handling and mixing characteristics.
HYDROPHILIC-LIPOPHILIC
BALANCE OF LECITHINS
ALC produces all-natural, soy-based and kosher lecithin products for a
variety of food and other applications. They cover a wide HLB range for
emulsification and come in liquid, granule and powder form. The following is
a guide in choosing the appropriate ALCOLEC lecithin for an emulsification
application.
Product Hydrophilic-Lipophilic
Balance Value
Product
|
HLB Value
|
|
2.0
|
|
4.0
|
|
4.0
|
|
8.0
|
|
8.0
|
|
8.0
|
- Lecithin can decrease mixing
times and improve results when combining dissimilar ingredients.
- Whether water-in-oil or
oil-in-water emulsion, the lecithin should be dispersed in the oil phase
first.
- For o/w emulsions, lecithin
functionality can be achieved anywhere from 5%-10% of the weight of oil.
- In w/o emulsions, lecithin
incorporation is substantially lower at 1%-5% of weight of oil.
Wetting and Instantizing
Lecithin provides rapid and complete wetting of powders into aqueous
systems. Similarly, instant powders require surface modifiers to improve
hydration and dissolution when they are reconstituted.
Depending on the individual
powder characteristics, some general guidelines help in selecting proper
lecithin addition rates:
- When using low fat powders,
lecithin products with a lower HLB value must be selected to retard the
wetting rate. Hydophilic (higher HLB) lecithin products promote wetting of
fatty powders.
- Particle size needs to be
considered. Smaller particles, with larger surface area, may require up to
2% lecithination whereas improved wetting properties of larger particles
can be accomplished at up to 0.25%.
Viscosity Modification
Lecithin products allow control of viscosity in liquid and semi-liquid
products. For example, chocolate and compound coatings utilize lecithin to
control viscosity. Lecithin greatly reduces the surface tension of fats,
allowing the particles of chocolate, sugar and other milk products to be
coated. This coating improves the foodstuff particle flowability and
significantly improves mixability. Typical usage levels for viscosity
modification range from 0.2%-0.6% of total product weight.
Release Agent
Lecithin products promote easy and complete separation of food from food
contact surfaces.
Release application systems
include dip tanks, aerosol sprays or air spray systems. In pan or belt
release applications, typical formulas consist primarily of vegetable oil
with 2% lecithin. Water-filled diptanks can contain up to 10% de-oiled
lecithin.
Separation Agent
Lecithin helps form a stable film barrier that prevents adhesion of food
products to one another. Direct incorporation, as in baked goods, allows for
better machinability and minimized sticking to the mixing vessel. Best
results are obtained when the lecithin is surface applied versus direct
incorporation, such as on processed cheese slices. Regulatory compliance
should be reviewed when direct incorporation is practiced to comply with FCC
standards of identity.
Special Processing Concerns
Salts
- Most food products contain
salt levels from 1%-2%.
- Salt content above 2% may
affect lecithin functionality.
pH
- Most lecithin products have
a pH of around 7.
- Lecithin is most effective
in formulas with a pH above 4.
Selecting the right
Lecithin compound
The following information is
provided as a guide for use of American Lecithin granular, powder and fluid
lecithin products in various formulations.
Solvent
Solubility Index for Alcolec© Lecithin Products
Solvent
|
Oil-Free Lecithin (Alcolec
Granular)
|
Fluid Lecithin (Alcolec
S/BS)
|
Water
|
D
|
I
|
Acetone
|
I
|
I
|
Acetonitrile
|
I
|
I
|
Benzene
|
S
|
S
|
Chlorodiflouromethane
|
S
|
S
|
Chloroform
|
S
|
S
|
Cyclohexanone
|
S
|
S
|
Diethyl
Ether
|
S
|
S
|
Dimethyl
Sulfoxide
|
I
|
I
|
Dioxane
|
I
|
I
|
Ethanol
|
I
|
I
|
Ethyl
Acetate
|
I
|
I
|
Glycerine
|
I
|
I
|
Heptanol
|
S
|
S
|
Hexane
|
S
|
S
|
Iso-amyl
Alcohol
|
I
|
I
|
Isooctane
|
S
|
S
|
Isopropyl Ether
|
S
|
S
|
Kerosene
|
S
|
S
|
Methanol
|
I
|
I
|
Methylene Chloride
|
S
|
S
|
Methyl
Ethyl Ketone
|
I
|
I
|
Methyl
Isobutyl Ketone
|
S
|
S
|
Mineral
Spirits
|
S
|
S
|
Petroleum Ether
|
S
|
S
|
Propylene Glycol
|
I
|
I
|
Pyridine
|
S
|
S
|
Tetrahydrofuran
|
S
|
S
|
Toluene
|
S
|
S
|
Index:
|
D
|
Dispersible by
use of hot water,
slightly alkalized
|
I
|
Insoluble
|
S
|
Soluble at 10%
(w/w) at 25°C
|
LECITHIN SELECTION CHART
Food Uses
|
Alcolec S
|
Alcolec BS
|
Alcolec Z-3
|
Alcolec F-100
|
Alcolec XTRA-A
|
Alcolec 495 |
Alcolec
Granules
|
Baked
Goods
|
|
|
|
|
|
|
|
Cheese
Products
|
|
|
|
|
|
|
|
Confections
|
|
|
|
|
|
|
|
Dairy
Products
|
|
|
|
|
|
|
|
Dietetic Products
|
|
|
|
|
|
|
|
Instant Foods
|
|
|
|
|
|
|
|
Margarines & Shortening
|
|
|
|
|
|
|
|
Meats
& Poultry
|
|
|
|
|
|
|
|
Processing & Coatings
|
|
|
|
|
|
|
|
Industrial Uses
|
Adhesives
|
|
|
|
|
|
|
|
Absorbents
|
|
|
|
|
|
|
|
Animal
Feeds
|
|
|
|
|
|
|
|
Ceramic & Glass
|
|
|
|
|
|
|
|
Cosmetics & Soaps
|
|
|
|
|
|
|
|
Detergents
|
|
|
|
|
|
|
|
Dust
Control
|
|
|
|
|
|
|
|
Dyes
|
|
|
|
|
|
|
|
Fertilizers
|
|
|
|
|
|
|
|
Inks
|
|
|
|
|
|
|
|
Leather
|
|
|
|
|
|
|
|
Magnetic Tape
|
|
|
|
|
|
|
|
Masonry & Asphalt
|
|
|
|
|
|
|
|
Metal
Processing
|
|
|
|
|
|
|
|
Paint
& Coatings
|
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|
Paper
|
|
|
|
|
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|
|
Pestcides
|
|
|
|
|
|
|
|
Petroleum/Oils
|
|
|
|
|
|
|
|
Polymers/Rubber
|
|
|
|
|
|
|
|
Textiles |
|
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